PUBLICATIONS

441. Ma, S.; Hill, C.K.; Olen, C.L.; Hartwig, J.F. Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction. J. Am. Chem. Soc.  2021143,  359-368.



440. Xi, Y.; Ma, S.; Hartwig, J.F. Catalytic asymmetric addition of an amine N–H bond across internal alkenes. Nature  2020588,  254-260.

436. Xi, Y.; Su, B.; Qi, X.; Pedram, S.; Liu, P.; Hartwig, J.F. Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydroboration of Disubstituted Alkenes. J. Am. Chem. Soc.  2020142,  18213-18222.



435. Richers, C.P.; Roediger, S.; Laserna, V.; Hartwig, J.F. Effects of Ligands on the Migratory Insertion of Alkenes into Rhodium–Oxygen Bonds. Chem. Sci.  202011,  10449-10456.



430. Hanna, S.; Wills, T.; Butcher, T.W.; Hartwig, J.F. Palladium-Catalyzed Oxidative Dehydrosilylation for Contra-Thermodynamic Olefin Isomerization. ACS Catal.  202010,  8736-8741.



424. Saper, N.I.; Ohgi, A.; Small, D.W.; Semba, K.; Nakao, Y.; Hartwig, J.F. Nickel-catalyzed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions. Nat. Chem.  202012,  276-283.



411. Hanna, S., Butcher, T.W., Hartwig, J.F. Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization. Org. Lett.  201921,  7129-7133.



405. Hanna, S., Holder, J.C., Hartwig, J.F. A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins. Angew. Chem. Int. Ed.  201958,  3368-3372.



351. Xi, Y.; Hartwig, J.F. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration. J. Am. Chem. Soc.  2016138,  6703-6706.



343. Xi, Y.; Butcher, T.W.; Zhang, J.; Hartwig, J.F. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angew. Chem. Int. Ed.  201655,  776-780.



340. Schramm, Y.; Takeuchi, M.; Semba, K.; Nakao, Y.; Hartwig, J.F. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel–N-Heterocyclic Carbene System. J. Am. Chem. Soc.  2015137,  12215–12218.



327. Bair, J.S.; Schramm, Y.; Sergeev, A.G.; Clot, E.; Eisenstein, O.; Hartwig, J.F. Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes. J. Am. Chem. Soc.  2014136,  13098-13101.



324. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes. J. Am. Chem. Soc.  2014136,  10625-10631.



312. Sevov, C.S; Zhou, J. (Steve); Hartwig, J.H. Iridium-Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles. J. Am. Chem. Soc.  2014136,  3200-3207.



302. Hanley, P.S.; Hartwig, J.H. Migratory Insertion of Alkenes into Metal–Oxygen and Metal–Nitrogen Bonds. Angew. Chem. Int. Ed.   201352,  8510-8525.



301. Strom, A.E.; Hartwig, J.H. One-Pot Anti-Markovnikov Hydroamination of Unactivated Alkenes by Hydrozirconation and Amination. J. Org. Chem.  201378,  8909-8914.



298. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed, Intermolecular Hydroetherification of Unactivated Aliphatic Alkenes with Phenols. J. Am. Chem. Soc.  2013135,  9303–9306.



293. Sevov, C.S.; Hartwig, J.F. Iridium-Catalyzed Intermolecular Asymmetric Hydroheteroarylation of Bicycloalkenes. J. Am. Chem. Soc.  2013135,  2116−2119.



279. Sevov, C.S.; Zhou, J.; Hartwig, J.F. Iridium-Catalyzed Intermolecular Hydroamination of Unactivated Aliphatic Alkenes with Amides and Sulfonamides. J. Am. Chem. Soc.  2012134,  11960–11963.



266. Hanley, P.S.; Hartwig, J.F.  Intermolecular Migratory Insertion of Unactivated Olefins into Palladium–Nitrogen Bonds. Steric and Electronic Effects on the Rate of Migratory Insertion. J. Am. Chem. Soc.   2011133,  15661-15673.



263. Zhijian Liu, Z.; Yamamichi, H.; Madrahimov, S.T.; Hartwig, J.F. Rhodium Phosphine-π-Arene Intermediates in the Hydroamination of Alkenes. J. Am. Chem. Soc  2011133,  2772-2782.



255. Julian, J.D.; Hartwig, J.F. Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex. J. Am. Chem. Soc.   2010132,  13813-13822.



245. Hanley, P.S.; Markovic, D.; Hartwig, J.F. Intermolecular Insertion of Ethylene and Octene into a Palladium-Amide Bond. Spectroscopic Evidence for an Ethylene Amido Intermediate. J. Am. Chem. Soc.  2010132,  6302-6303.



234. Tye, J.W.; Hartwig, J.F.  Computational Studies on the Relative Rates for Migratory Insertions of Alkenes into Square-Planar Rhodium–Methyl, –Amide, and –Hydroxide Complexes. J. Am. Chem. Soc.   2009131,  14703.



215. Zhou, J. and J.F. Hartwig Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity.. J. Am. Chem. Soc.  2008130,  12220-12221.



210. Liu, Z., and J.F. Hartwig Mild, Rhodium-Catalyzed Intramolecular Hydroamination of Unactivated Terminal and Internal Olefins with Primary and Secondary Amines.. J. Am. Chem. Soc.  2008130,  1570-1571.



198. Johns, A.M., Liu, Z., and J. F. Hartwig Primary tert- and sec-Allylamines via Palladium-Catalyzed Hydroamination and Allylic Substitution with Hydrazine and Hydroxylamine Derivatives.. Angew. Chem. Int. Ed.  200746,  7259-7261.



192. Herzon, S. B., and J. F. Hartwig Direct, Catalytic Hydroaminoalkylation of Unactivated Olefins with N-Alkyl Arylamines. J. Am. Chem. Soc.  2007129,  6690-6691.



180. Rosenfeld, D. C., Shekhar, S., Takemiya, A., Utsunomiya, M., and J. F. Hartwig Hydroamination and Hydroalkoxylation Catalyzed by Triflic Acid. Parallels to Reactions Initiated with Metal Triflates. Org. Lett.  20068,  4179-4182.



173. Sakai, N., Ridder, A., J. F. Hartwig Tropene Derivatives by Sequential Intermolecular and Transannular, Intramolecular Palladium-Catalyzed Hydroamination of Cycloheptatriene. J. Am. Chem. Soc.  2006128,  8134-8135.



172. Johns, A.M., Sakai, N., Ridder, A., and J. F. Hartwig Direct Measurement of the Thermodynamics of Vinylarene Hydroamination. J. Am. Chem. Soc.  2006128,  9306-9307.



169. Johns, A. M., Utsunomiya, M., Incarvito, C. D., and J. F. Hartwig A Highly Active Palladium Catalyst for Intermolecular Hydroamination. Factors that Control Reactivity and Additions of Functionalized Anilines to Dienes and Vinylarenes. J. Am. Chem. Soc.  2006128,  1828-1839.



153. Takaya, J. and J. F. Hartwig Mechanistic Studies of Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes: Intermediates and Evidence for Catalysis through p-Arene Complexes. J. Am. Chem. Soc.  2005127,  5756-5757.



131. Utsunomiya, M. and J. F. Hartwig Ruthenium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc.  2005126,  2702-2703.



121. Kanzelberger, M., Zhang, X., Emge, T. J., Goldman, A. S., Zhao, J., Incarvito, C. D., and J. F. Hartwig Distinct Thermodynamics for the Formation and Cleavage of N-H Bonds in Aniline and Ammonia. Directly-Observed Reductive Elimination of Ammonia from an Isolated Amido Hydride Complex. J. Am. Chem. Soc.  2003125,  13644-13645.



112. Utsunomiya, M., Kawatsura, M., and J. F. Hartwig Palladium-Catalyzed Equilibrium Addition of Acidic OH Groups across Dienes. Angew. Chem. Int. Ed.  200342,  5865-5868.

111. Utsunomiya, M., Kuwano, R., Kawatsura, M., and J. F. Hartwig Rhodium-Catalyzed Anti-Markovnikov Hydroamination of Vinylarenes. J. Am. Chem. Soc.  2003125,  5608-5609.



110. Utsunomiya, M. and J. F. Hartwig Intermolecular, Markovnikov Hydroamination of Vinylarenes with Alkylamines. J. Am. Chem. Soc.  2003125,  14286-14287.



93. Nettekoven, U. and J. F. Hartwig A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. J. Am. Chem. Soc.  2002124,  1166-1167.



91. Pawlas, J., Nakao, Y., Kawatsura, M., J. F. Hartwig A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: Catalyst selection, scope, and mechanism. J. Am. Chem. Soc.  2002124,  3669-3679.



89. Schlummer, B. and J. F. Hartwig Bronsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Org. Lett.  20024,  1471-1474.



79. Kawatsura, M. and J. F. Hartwig Transition metal-catalyzed addition of amines to acrylic acid derivatives. A high-throughput method for evaluating hydroamination of primary and secondary alkylamines. Organometallics  200120,  1960-1964.



75. Lober, O., Kawatsura, M., and J. F. Hartwig Palladium-catalyzed hydroamination of 1,3-dienes: A colorimetric assay and enantioselective additions. J. Am. Chem. Soc.  2001123,  4366-4367.

65. Kawatsura, M. and J. F. Hartwig Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines. J. Am. Chem. Soc.  2000122,  9546-9547.