Publications

C-C Bond Forming Cross-Couplings C-X Bond Forming Cross-Couplings Olefin Functionalization Iridium-Catalyzed Allylic Substitution C-H Bond Functionalization Catalysis for Sustainable Energy & Polymers Fluorination and Fluoroalkylation Main-Group-Transition Metal Organometallics New Organometallic Reactions High Throughput Screening Combining Organometallics with Biocatalysis Reviews Commentary and Book Chapters
145. Cook, K. S., Incarvito, C. D., Webster, C. E., Fan, Y., Hall, M. B. and J. F. Hartwig Rhodium Silyl Boryl Hydride Complexes: Comparison of Bonding and the Rates of Elimination of Borane, Silane, and Dihydrogen. Angew. Chem. Int. Ed.  2004,  43,  5474-5477.

128. Anastasi, N. R., Waltz, K. M., Weerakoon, W. L., and J. F. Hartwig A short synthesis of tetraalkoxydiborane(4) reagents. Organometallics  2003,  22,  365-369.

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67. Hartwig, J. F. and C. N. Muhoro Mechanistic studies of titanocene-catalyzed alkene and alkyne hydroboration: Borane complexes as catalytic intermediates. Organometallics  2000,  19,  30-38.

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64. Schlecht, S. and J. F. Hartwig s-borane complexes of manganese and rhenium. J. Am. Chem. Soc.  2000,  122,  9435-9443.

54. Muhoro, C. N., He, X. M., and J. F. Hartwig Titanocene borane sigma-complexes. J. Am. Chem. Soc.  1999,  121,  5033-5046.

29. Muhoro, C. N.; Hartwig, J. F. Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex. Angew. Chem. Int. Ed. Engl.  1997,  36,  1510-1512.

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25. Hartwig, J. F. and X. M. He Structural and reaction chemistry of tungstenocene boryl complexes. Organometallics  1996,  15,  5350-5358.

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24. Hartwig, J. F., Muhoro, C. N., He, X., Eisenstein, O., Bosque, R., and F. Maseras Catecholborane bound to titanocene. Unusual coordination of ligand sigma-bonds. J. Am. Chem. Soc.  1996,  118,  10936-10937.

21. Hartwig, J. F.; He, X. Reactivity of Tungstenocene with B-B and B-H Bonds versus C-H Bonds. Angew. Chem. Int. Ed. Engl.  1996,  35,  315-317.

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20. He, X. M. and J. F. Hartwig True metal-catalyzed hydroboration with titanium. J. Am. Chem. Soc.  1996,  118,  1696-1702.

19. He, X. M. and J. F. Hartwig Boryls bound to iron carbonyl. Structure of a rare bis(boryl) complex, synthesis of the first anionic boryl, and reaction chemistry that includes the synthetic equivalent of boryl anion transfer. Organometallics  1996,  15,  400-407.

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15. Rablen, P. R. and J. F. Hartwig Accurate borane sequential bond dissociation energies by high-level ab initio computational methods. J. Am. Chem. Soc.  1996,  118,  4648-4653.

7. Hartwig, J. F. and S. R. De Gala A Continuum Resulting from Equilibrium between 2 Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes - p-Bonding in a d2 Boryl System and the First d0 Boryl Complex. J. Am. Chem. Soc.  1994,  116,  3661-3662.

6. Hartwig, J. F., Bhandari, S., and P. R. Rablen Addition of Catecholborane to a Ruthenium-Alkyl - Evidence for Sigma-Bond Metathesis with a Low-Valent, Late Transition-Metal. J. Am. Chem. Soc.  1994,  116,  1839-1844.

4. Rablen, P. R., Hartwig, J. F., and S. P. Nolan First Transition Metal-Boryl Bond-Energy and Quantitation of Large Differences in Sequential Bond-Dissociation Energies of Boranes. J. Am. Chem. Soc.  1994,  116,  4121-4122.

3. Hartwig, J. F. and S. Huber Transition-Metal Boryl Complexes - Structure and Reactivity of CpFe(CO)2Bcat and CpFe(CO)2BPh2. J. Am. Chem. Soc.  1993,  115,  4908-4909.