Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex
![Synthesis, Structure, and Reactivity of [Cp<sub>2</sub>Ti(HBcat)(PMe<sub>3</sub>)]: A Monoborane σ Complex](/static/img/pubs/toc_29.jpg)
A significant B![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
H interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.
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