Synthesis, Structure, and Reactivity of [Cp2Ti(HBcat)(PMe3)]: A Monoborane σ Complex
Angew. Chem. Int. Ed. Engl., 1997, 36 (1510-1512)
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Abstract
A significant B
H interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.
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H interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.