Synthesis, Structure, and Reactivity of [Cp<sub>2</sub>Ti(HBcat)(PMe<sub>3</sub>)]: A Monoborane &sigma; Complex

Abstract

A significant B[BOND]H interaction is detected in the TiII compound 1, the first monoborane σ complex. This complex undergoes ligand substitution with CO to form 2 and transfers catecholborane to diphenylacetylene to form 3.
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