PUBLICATIONS

409. He, Z.T., Jiang, X., Hartwig, J.F. Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts. J. Am. Chem. Soc.  2019141,  13066-13073.



403. He, Z.T., Hartwig, J.F. Enantioselective α-functionaliations of ketones via allylic substitution of silyl enol ethers. Nat. Chem.  201911,  177.



357. Chen, M.; Hartwig, J.F. Iridium-​Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angew. Chem. Int. Ed.  201655,  11651-11655.



349. Jiang, X.; Chen, W.; Hartwig, J.F. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic -Alkoxy Ketones. Angew. Chem. Int. Ed.  201655,  5819-5823.



342. Madrahimov, S.T.; Li, Q.; Sharma, A.; Hartwig, J.F. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. J. Am. Chem. Soc.  2015137,  14968-14981.



341. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. J. Am. Chem. Soc.  2015137,  13972-13979.



326. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones. Angew. Chem. Int. Ed.  201453,  1-6.



318. Chen, M.; Hartwig, J.F. Iridium-Catalyzed Enantioselective Allylic Substitution of Unstabilized Enolates Derived from α,β-Unsaturated Ketones. Angew. Chem. Int. Ed.  201453,  1-6.



309. Chen, W.; Hartwig, J.F. Cation Control of Diastereoselectivity in Iridium-Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H-Oxazol-4-ones and 5H-Thiazol-4-ones. J. Am. Chem. Soc.  2014136,  377-382.



304. Sharma, A.; Hartwig, J.F. Enantioselective Functionalization of Allylic C–H Bonds Following a Strategy of Functionalization and Diversification. J. Am. Chem. Soc.  2013135,  17983-17989.



294. Chen, W.; Hartwig, J.F. Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion. J. Am. Chem. Soc.  2013135,  2068−2071.



284. Chen, W.; Hartwig, J.F. Iridium-Catalyzed Regioselective and Enantioselective Allylation of Trimethylsiloxyfuran. J. Am. Chem. Soc.  2012134,  15249–15252.



252. Stanley, L.M.; Hartwig, J.F. Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution. Acc. Chem. Res.  201043,  1461-1475.



247. Stanley, L. M.; Bai, C.; Ueda, M.; Hartwig, J. F. Iridium-Catalyzed Kinetic Asymmetric Transformations of Racemic Allylic Benzoates. J. Am. Chem. Soc.   2010132,  8918-8920.



235. Ueda, M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution with Aromatic and Aliphatic Sulfinates. Org. Lett.  200912,  92-94.



232. Stanley, L.M.; Hartwig, J.F. Iridium-Catalyzed Regio- and Enantioselective N-Allylation of Indoles. Angew. Chem. Int. Ed.   200948,  7841.

231. Pouy, M.J; Stanley, L.M.; Hartwig, J.F. Enantioselective, Iridium-Catalyzed Monoallylation of Ammonia.. J. Am. Chem. Soc.  2009131,  11312–11313.



225. Madrahimov, S.T.; Markovic, D.; Hartwig, J.F. The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reaction. J. Am. Chem. Soc.  2009131,  7228-7229.



209. Ueno, S., and J.F. Hartwig Direct, Iridium-Catalyzed Asymmetric Allylic Etherification with Aliphatic Alcohols.. Angew. Chem. Int. Ed.  200847,  1928-1931.



197. Markovic, D. and J. F. Hartwig Resting State and Kinetic Studies on the Asymmetric Allylic Substitutions Catalyzed by Iridium-Phosphoramidite Complexes.. J. Am. Chem. Soc.  2007129,  11680-11681.



196. Pouy, M. J., Leitner, A., Weix, D. J., Ueno, S. and J. F. Hartwig Enantioselective Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. Org. Lett.  20079,  3949-3952.



194. Weix, D. J. and J. F. Hartwig Regioselective and Enantioselective Iridium-Catalyzed Allylation of Enamines. J. Am. Chem. Soc.  2007129,  7720-7721.



193. Yamashita, Y., Gopalarathnam, A., and J. F. Hartwig Iridium-Catalyzed, Asymmetric Amination of Allylic Alcohols Activated by Lewis Acids. J. Am. Chem. Soc.  2007129,  7508-7509.



179. Shekhar, S., Trantow, B., Leitner, A., and J. F. Hartwig Sequential Catalytic Isomerization and Allylic Substitution. Conversion of Racemic Branched Allylic Carbonates to Enantioenriched Allylic Substitution Products. J. Am. Chem. Soc.  2006128,  11770-11771.



161. Graening, T. and J. F. Hartwig Iridium-Catalyzed Regio- and Enantioselective Allylation of Ketone Enolates. J. Am. Chem. Soc.  2005127,  17192-17193.



157. Leitner, A., Shekhar, S., Pouy, M. J., and J. F. Hartwig A Simple Iridium Catalyst with a Single Resolved Stereocenter for Enantioselective Allylic Amination. Catalyst Selection from Mechanistic Analysis. J. Am. Chem. Soc.  2005127,  15506-15514.



156. Leitner, A., Shu, C., and J. F. Hartwig Effects of Catalyst Activation and Ligand Steric Properties on the Enantioselective Allylation of Amines and Phenoxides. Org. Lett.  20057,  1093-1096.



139. Leitner, A., Shu, C., and J. F. Hartwig Editing the Stereochemical Elements in an Iridium Catalyst for Enantioselective Allylic Amination. Proc. Nat. Acad. Sci. U.S.A.  2004101,  5830-5833.

134. Shu, C., Leitner, A. and J. F. Hartwig Enantioselective Allylation of Aromatic Amines after In Situ Generation of an Activated Cyclometalated Iridium Catalyst. Angew. Chem. Int. Ed.  200443,  4797-4800.

133. Shu, C. and J. F. Hartwig Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Angew. Chem. Int. Ed.  200443,  4794-4797.

120. Kiener, C. A., Shu, C., Incarvito, C. D., and J. F. Hartwig Identification of an Activated Catalyst in the Iridium-Catalyzed Allylic Amination and Etherification. Increased Rates, Scope, and Selectivity. J. Am. Chem. Soc.  2003125,  14272 -14273.



118. Lopez, F., Ohmura, T., and J. F. Hartwig Regio- and Enantioselective Iridium-Catalyzed Intermolecular Allylic Etherification of Achiral Allylic Carbonates with Phenoxides.. J. Am. Chem. Soc.  2003125,  3426-3427.



92. Ohmura, T. and J. F. Hartwig Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. J. Am. Chem. Soc.  2002124,  15164-15165.