438. Wang, J.Y.; Choi, K.; Zuend, S.J.; Borate, K.; Hartwig, J.F.
Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine.
Angew. Chem. Int. Ed.2020,
60, 399-408.
322. Green, R.A.; Hartwig, J.F.
Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts.
Org. Lett.2014,
16, 4388−4391.
310. Ge. S.; Green, R.A.; Hartwig, J.F.
Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex.
J. Am. Chem. Soc.2014,
136, 1617-1627.
292. Fier, P.S.; Luo, J.; Hartwig, J.F.
Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex.
J. Am. Chem. Soc.2013,
135, 2552−2559.
285. Chen, C.; Weng, Z.; Hartwig, J.F.
Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides.
Organometallics2012,
31, 8031–8036.
254. Giri, R.: Hartwig, J.F.
Cu(I) Amido Complexes in the Ullmann Reaction. Reactions of Cu(I)-Amido Complexes with Iodoarenes with and without Autocatalysis by CuI.
J. Am. Chem. Soc. 2010,
132, 15860-15863.
246. Fernandez-Rodriguez, M.A.; Hartwig, J.F.
One-Pot Synthesis of Unsymmetrical Diaryl Thioethers by Palladium-Catalyzed Coupling of Two Aryl Bromides and a Thiol Surrogate.
Chem. Eur. J.2010,
16, 2355-2359.
230. Vo, G.D.; Hartwig, J.F.
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
J. Am. Chem. Soc.2009,
131, 11049-11061.
227. Alvaro, E.; Hartwig, J.F.
Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium.
J. Am. Chem. Soc.2009,
131, 7858–7868.
224. Fernandez-Rodríguez, M.A.; Hartwig, J.F.
A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides.
J. Org. Chem.2009,
74, 1663-1672.
222. Hartwig, J.F.
Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides.
Acc. Chem. Res.2008,
41, 1534-1544.
213. Shen, Q. and J.F. Hartwig
[(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides..
Org. Lett.2008,
18, 4109-4112.
212. Tye, J.W., Weng, Z., Johns, A. M., Incarvito, C. D., and J. F. Hartwig
Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides..
J. Am. Chem. Soc.2008,
130, 9971-9983.
207. Shen, Q., Ogata, T., and J.F. Hartwig
Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides and Iodides: Scope and Structure-Activity Relationships..
J. Am. Chem. Soc.2008,
130, 6586-6596.
205. Hagedorn, K.V., Varnavski, O., Hartwig, J.F; Goodson III, T.
Exciton Trapping in an Organic Dendrimer Possessing No Energy Gradient..
J. Phys. Chem. C.2008,
112, 2235-2238.
199. Stambuli, J.P., Weng, Z., Incarvito, C.D., and J. F. Hartwig
Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides..
Angew. Chem. Int. Ed.2007,
46, 7674-7677.
195. Shen, Q. and J. F. Hartwig
Lewis Acid Acceleration of C-N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides.
J. Am. Chem. Soc.2007,
129, 7734-7735.
187. Shekhar, S., and J. F. Hartwig
Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd[P(tBu3)]2.
Organometallics2007,
26, 340-351.
184. Johns, A. M, Tye, J. W., and J. F. Hartwig
Relative Rates for the Aminations of h3-Allyl and h3-Benzyl Complexes of Palladium.
J. Am. Chem. Soc.2006,
128, 16010-16011.
182. Fernandez-Rodríguez, M. A., Shen, Q., and J. F. Hartwig
Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols.
Chem. Eur. J.2006,
12, 7782-7796.
175. Fujita, K.I., Yamashita, M, Puschmann, F., Alvarez-Falcon, M.M., Incarvito, C.D., and J. F. Hartwig
Organometallic Chemistry from Amidate Complexes. Reductive elimination of N-Aryl Amidates from Palladium(II).
J. Am. Chem. Soc.2006,
128, 9044-9045.
168. Fernández-Rodríguez, M. A., Shen, Q., and J. F. Hartwig
A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols.
J. Am. Chem. Soc.2006,
128, 2180-2181.
167. Shekhar, S., Ryberg, P., and J. F. Hartwig
Oxidative Addition of Phenyl Bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for Addition to Pd(BINAP).
Org. Lett.2006,
8, 851-854.
166. Shekhar, S., Ryberg, P., Hartwig, J. F., Mathew, J. S., Blackmond, D. G., Strieter, E. R., and S. L. Buchwald
Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes.
J. Am. Chem. Soc.2006,
128, 3584-3591.
164. Barrios-Landeros, F. and J. F. Hartwig
Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands.
J. Am. Chem. Soc.2005,
127, 6944-6945.
163. Bae, C., Hartwig, J. F., Boaen Harris, N. K., Long, R. O., Anderson, K. S., and M. A. Hillmyer
Catalytic Hydroxylation of Polypropylenes.
J. Am. Chem. Soc.2005,
127, 767-776.
158. Lee, D.-Y. and J. F. Hartwig
Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates.
Org. Lett.2005,
7, 1169-1172.
154. Shen, Q., Shekhar, S., Stambuli, J. P., and J. F. Hartwig
Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles..
Angew. Chem. Int. Ed.2005,
44, 1371-1375.
150. Yan, X. Z., Pawlas, J., Goodson, T., III and J. F. Hartwig
Polaron Delocalization in Ladder Macromolecular Systems.
J. Am. Chem. Soc.2005,
127, 9105-9116.
149. Zhao, J., Goldman, A. S., and J. F. Hartwig
Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex.
Science2005,
307, 1080-1082.
142. Krug, C. and J. F. Hartwig
Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions.
Organometallics2004,
23, 4594-4607.
135. Shekhar, S. and J. F. Hartwig
Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes..
J. Am. Chem. Soc.2004,
126, 13016-13027.
125. Hooper, M. W., Utsunomiya, M., and J. F. Hartwig
Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides.
J. Org. Chem.2003,
68, 2861-2873.
124. Hooper, M. W. and J. F. Hartwig
Understanding the Coupling of Heteroaromatic Substrates: Synthesis, Structures, and Reductive Eliminations of Heteroarylpalladium Amido Complexes.
Organometallics2003,
22, 3394-3403.
117. Mann, G., Shelby, Q., Roy, A. H., and J. F. Hartwig
Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II).
Organometallics2003,
22, 2775-2789.
116. Roy, A. H. and J. F. Hartwig
Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes.
J. Am. Chem. Soc.2003,
125, 13944-13945.
113. Stauffer, S. R. and J. F. Hartwig
Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study..
J. Am. Chem. Soc.2003,
125, 6977-6985.
108. Yamashita, M., Cuevas Vicario, J. V., and J. F. Hartwig
Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres.
J. Am. Chem. Soc.2003,
125, 16347-16360.
104. Alcazar-Roman, L. M. and J. F. Hartwig
Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine.
Organometallics2002,
21, 491-502.
94. Kuwano, R., Utsunomiya, M., and J. F. Hartwig
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
J. Org. Chem.2002,
67, 6479-6486.
90. Ranasinghe, M. I., Varnavski, O. P., Pawlas, J., Hauck, S. I., Louie, J., Hartwig, J. F., and T. Goodson III
Femtosecond excitation energy transport in triarylamine dendrimers.
J. Am. Chem. Soc.2002,
124, 6520-6521.
87. Stambuli, J. P., Buhl, M., and J. F. Hartwig
Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand.
J. Am. Chem. Soc.2002,
124, 9346-9347.
83. Chae, H. K., Eddaoudi, M., Kim, J., Hauck, S. I., Hartwig, J. F., O'Keeffe, M., and O. M. Yaghi
Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1).
J. Am. Chem. Soc.2001,
123, 11482-11483.
77. Lee, S., M. Jorgensen, and J. F. Hartwig
Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.
Org. Lett.2001,
3, 2729-2732.
70. Shelby, Q.; Kataoka, N.; Mann, G.; Hartwig, J.F.
Unusual in situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C-O Bond Formation.
J. Am. Chem. Soc.2000,
122, 10718-10719.
69. Alcazar-Roman, L. M., Hartwig, J. F., Rheingold, A. L., Liable-Sands, L. M., and I. A. Guzei
Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition.
J. Am. Chem. Soc.2000,
122, 4618-4630.
63. Stauffer, S. R., Lee, S., Stambuli, J. P., Hauck, S. I., and J. F. Hartwig
High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.
Org. Lett.2000,
2, 1423-1426.
60. Goodson, F. E., Hauck, S. I., and J. F. Hartwig
Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines.
J. Am. Chem. Soc.1999,
121, 7527-7539.
58. Hartwig, J. F., Kawatsura, M., Hauck, S. I., Shaughnessy, K. H., and L. M. Alcazar-Roman
Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand.
J. Org. Chem.1999,
64, 5575-5580.
57. Hauck, S. I., Lakshmi, K. V. and J. F. Hartwig
Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals.
Org. Lett.1999,
1, 2057-2060.
55. Mann, G., Incarvito, C. D., Rheingold, A. L., and J. F. Hartwig
Palladium-catalyzed C-O coupling involving unactivated aryl halides. Sterically induced reductive elimination to form the C-O bond in diaryl ethers.
J. Am. Chem. Soc.1999,
121, 3224-3225.
50. Goodson, F. E. and J. F. Hartwig
Regiodefined poly(N-arylaniline)s and donor-acceptor copolymers via palladium-mediated amination chemistry.
Macromolecules1998,
31, 1700-1703.
49. Hamann, B. C. and J. F. Hartwig
Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates.
J. Am. Chem. Soc.1998,
120, 12706-12706.
47. Hamann, B. C. and J. F. Hartwig
Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations.
J. Am. Chem. Soc.1998,
120, 3694-3703.
46. Hartwig, J. F.
Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides.
Acc. Chem. Res.1998,
31, 852-860.
45. Hartwig, J. F.
Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism.
Angew. Chem. Int. Ed.1998,
37, 2047-2067.
44. Hartwig, J. F.
Synthesis, structure, and reactivity of a palladium hydrazonato complex: A new type of reductive elimination reaction to form C-N bonds and catalytic arylation of benzophenone hydrazone.
Angew. Chem. Int. Ed.1998,
37, 2090-2093.
43. Louie, J. and J. F. Hartwig
The largest discrete oligo(m-aniline). An exponential growth strategy using palladium-catalyzed amination of aryl sulfonates.
Macromolecules1998,
31, 6737-6739.
42. Mann, G., Baranano, D., Hartwig, J. F., Rheingold, A. L., and I. A. Guzei
Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation.
J. Am. Chem. Soc.1998,
120, 9205-9219.
41. Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas
Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes.
J. Am. Chem. Soc.1998,
120, 827-828.
38. Baranano, D.; Mann, G., and Hartwig, J. F.
Nickel and palladium-catalyzed cross-couplings that form carbon-heteroatom and carbon-element bonds.
Current Organic Chemistry1997,
1, 287-305.
33. Louie, J., Hartwig, J. F., and A. J. Fry
Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination.
J. Am. Chem. Soc.1997,
119, 11695-11696.
32. Louie, J., Driver, M. S., Hamann, B. C., and J. F. Hartwig
Palladium-catalyzed amination of aryl triflates and importance of triflate addition rate.
J. Org. Chem.1997,
62, 1268-1273.
31. Mann, G. and J. F. Hartwig
Palladium-catalyzed formation of diaryl ethers from aryl bromides. Electron poor phosphines enhance reaction yields.
Tetrahedron Letters1997,
38, 8005-8008.
30. Mann, G. and J. F. Hartwig
Nickel- vs palladium-catalyzed synthesis of protected phenols from aryl halides.
J. Org. Chem.1997,
62, 5413-5418.
27. Driver, M. S. and J. F. Hartwig
A second-generation catalyst for aryl halide amination: Mixed secondary amines from aryl halides and primary amines catalyzed by (DPPF)PdCl2.
J. Am. Chem. Soc.1996,
118, 7217-7218.
22. Hartwig, J. F., Richards, S., Baranano, D., and F. Paul
Influences on the relative rates for C-N bond-forming reductive elimination and beta-hydrogen elimination of amides. A case study on the origins of competing reduction in the palladium-catalyzed amination of aryl halides.
J. Am. Chem. Soc.1996,
118, 3626-3633.
17. Louie, J., F. Paul, and J. F. Hartwig
Catalysis with platinum-group alkylamido complexes, the active palladium amide in catalytic aryl halide aminations as deduced from kinetic data and independent generation.
Organometallics1996,
15, 2794-2805.
16. Mann, G. and J. F. Hartwig
Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III).
J. Am. Chem. Soc.1996,
118, 13109-13110.
14. Baranano, D. and J. F. Hartwig
Carbon-Heteroatom Bond-Forming Reductive Elimination - Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects During Formation of Aryl Sulfides.
J. Am. Chem. Soc.1995,
117, 2937-2938.
13. Driver, M. S. and J. F. Hartwig
A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by 3-Coordinate Intermediates.
J. Am. Chem. Soc.1995,
117, 4708-4709.
12. Paul, F., Patt, J., and J. F. Hartwig
Structural Characterization and Simple Synthesis of (Pd[P(O-Tol)3]2), Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides, and Corresponding Monometallic Amine Complexes.
Organometallics1995,
14, 3030-3039.
11. Hartwig, J. F. and F. Paul
Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a 2-Coordinate Palladium(0) Complex, Bis(Tri-O-Tolylphosphine)Palladium(0).
J. Am. Chem. Soc.1995,
117, 5373-5374.
10. Louie, J. and J. F. Hartwig
Transmetalation Involving Organotin Aryl, Thiolate, and Amide Compounds - an Unusual Type of Dissociative Ligand Substitution-Reaction.
J. Am. Chem. Soc.1995,
117, 11598-11599.
9. Louie, J. and J. F. Hartwig
Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides - Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents.
Tetrahedron Letters1995,
36, 3609-3612.
5. Paul, F., Patt, J., and J. F. Hartwig
Palladium-Catalyzed Formation of Carbon-Nitrogen Bonds - Reaction Intermediates and Catalyst Improvements in the Hetero Cross-Coupling of Aryl Halides and Tin Amides.
J. Am. Chem. Soc.1994,
116, 5969-5970.
