[(CyPF-tBu)PdCl2]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides.
An air- and moisture-stable palladium catalyst, [(CyPF-tBu)PdCl2] (1), for coupling of heteroaryl chlorides, bromides, and iodides with a variety of primary amines is described. Most of these reactions occurred in high yield with 0.001−0.05 mol % catalyst loading. The reactions tolerated a wide range of functional groups.
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