Publications

461. Choi K, Mormino MG, Kalkman ED, Park J, Hartwig JF Palladium-Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes. Angew. Chem. Int. Ed.  2022None,  ASAP.



434. Butcher, T.W.; Yang, J.L.; Hartwig, J.F. Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups. Org. Lett.  202022,  6805-6809.



429. Butcher, T.W.; Yang, J.L.; Amberg, W.M.; Watkins, N.B.; Wilkinson, N.D.; Hartwig, J.F. Desymmetrization of difluoromethylene groups by C-F bond activation. Nature  2020583,  548-553.



422. Dorel, R.; Boehm, P.; Schwinger, D.P.; Hartwig, J.F. Copper-Mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride. Chem. Eur. J.  202026,  1759-1762.



421. Yoritate, M.; Londregan, A.T.; Lian, Y.; Hartwig, J.F. Sequential Xanthalation and O‑Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers. J. Org. Chem.  201984,  15767-15776.



416. Kalkman, E.D.; Mormino, M.G.; Hartwig, J.F. Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoroethyl Complexes of Substituted Bipyridines. J. Am. Chem. Soc.  2019141,  19458-19465.



377. Fier, P.S.; Hartwig, J.F. Site-Selective C-H Fluorination of Pyridines and Diazines with AgF2. Org. Synth.  201794,  46-53.



355. Zhang, Q.; Brusoe, A.T.; Mascitti, V.; Hesp, K.D.; Blakemore, D.C.; Kohrt, J.T.; Hartwig Fluorodecarboxylation for the synthesis of trifluoromethyl aryl ethers. Angew. Chem. Int. Ed.  201655,  9758-9762.



353. Morstein, J.; Hou, H.; Cheng, C.; Hartwig, J.F. Trifluoromethylation of Arylsilanes with [(phen)CuCF3]. Angew. Chem. Int. Ed.  201655,  8054-8057.



283. Litvinas, N.D.; Fier, P.S.; Hartwig, J.F. A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF. Angew. Chem. Int. Ed.  201251,  536-539.



277. Fier, P.S.; Hartwig, J.F. Copper-Mediated Fluorination of Aryl Iodides. J. Am. Chem. Soc.  2012134,  10795-10798.



270. Morimoto, H.; Tsubogo, T.; Litvinas, N.D.; Hartwig, J.F. A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides. Angew. Chem. Int. Ed.   201150,  3793–3798.