Publications

C-C Bond Forming Cross-Couplings C-X Bond Forming Cross-Couplings Olefin Functionalization Iridium-Catalyzed Allylic Substitution C-H Bond Functionalization Catalysis for Sustainable Energy & Polymers Fluorination and Fluoroalkylation Main-Group-Transition Metal Organometallics New Organometallic Reactions High Throughput Screening Combining Organometallics with Biocatalysis Reviews Commentary and Book Chapters
461. Choi, K.; Mormino, M.G.; Kalkman, E.D.; Park, J.; Hartwig, J.F. Palladium-Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes. Angew. Chem. Int. Ed.  2022,  61,  e202208204.

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434. Butcher, T.W.; Yang, J.L.; Hartwig, J.F. Copper-Catalyzed Defluorinative Borylation and Silylation of gem-Difluoroallyl Groups. Org. Lett.  2020,  22,  6805-6809.

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429. Butcher, T.W.; Yang, J.L.; Amberg, W.M.; Watkins, N.B.; Wilkinson, N.D.; Hartwig, J.F. Desymmetrization of difluoromethylene groups by C-F bond activation. Nature  2020,  583,  548-553.

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422. Dorel, R.; Boehm, P.; Schwinger, D.P.; Hartwig, J.F. Copper-Mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride. Chem. Eur. J.  2020,  26,  1759-1762.

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421. Yoritate, M.; Londregan, A.T.; Lian, Y.; Hartwig, J.F. Sequential Xanthalation and O‑Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers. J. Org. Chem.  2019,  84,  15767-15776.

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416. Kalkman, E.D.; Mormino, M.G.; Hartwig, J.F. Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoroethyl Complexes of Substituted Bipyridines. J. Am. Chem. Soc.  2019,  141,  19458-19465.

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377. Fier, P.S.; Hartwig, J.F. Site-Selective C-H Fluorination of Pyridines and Diazines with AgF2. Org. Synth.  2017,  94,  46-53.

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355. Zhang, Q.; Brusoe, A.T.; Mascitti, V.; Hesp, K.D.; Blakemore, D.C.; Kohrt, J.T.; Hartwig Fluorodecarboxylation for the synthesis of trifluoromethyl aryl ethers. Angew. Chem. Int. Ed.  2016,  55,  9758-9762.

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353. Morstein, J.; Hou, H.; Cheng, C.; Hartwig, J.F. Trifluoromethylation of Arylsilanes with [(phen)CuCF3]. Angew. Chem. Int. Ed.  2016,  55,  8054-8057.

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283. Litvinas, N.D.; Fier, P.S.; Hartwig, J.F. A General Strategy for the Perfluoroalkylation of Arenes and Arylbromides by Using Arylboronate Esters and [(phen)CuRF. Angew. Chem. Int. Ed.  2012,  51,  536-539.

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277. Fier, P.S.; Hartwig, J.F. Copper-Mediated Fluorination of Aryl Iodides. J. Am. Chem. Soc.  2012,  134,  10795-10798.

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270. Morimoto, H.; Tsubogo, T.; Litvinas, N.D.; Hartwig, J.F. A Broadly Applicable Copper Reagent for Trifluoromethylations and Perfluoroalkylations of Aryl Iodides and Bromides. Angew. Chem. Int. Ed.   2011,  50,  3793–3798.

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