Publications

C-C Bond Forming Cross-Couplings C-X Bond Forming Cross-Couplings Olefin Functionalization Iridium-Catalyzed Allylic Substitution C-H Bond Functionalization Catalysis for Sustainable Energy & Polymers Fluorination and Fluoroalkylation Main-Group-Transition Metal Organometallics New Organometallic Reactions High Throughput Screening Combining Organometallics with Biocatalysis Reviews Commentary and Book Chapters
346. Wang, D.Y.; Choliy, Y.; Haibach, M.C.; Hartwig, J.F.; Krogh-Jespersen, K.; Goldman, A.S Assessment of the Electronic Factors Determining the Thermodynamics of "Oxidative Addition" of C–H and N–H Bonds to Ir(I) Complexes. J. Am. Chem. Soc.  2016,  138,  149-163.

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282. Hanley, P.S.; Marquard, S.L.; Cundari, T.R.; Hartwig, J.F. Reductive Elimination of Alkylamines from Low-Valent, Alkylpalladium(II) Amido Complexes. J. Am. Chem. Soc.  2012,  134,  15281–15284.

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267. Marquard,  S.L.; Hartwig, J.F C(sp3)–O Bond-Forming Reductive Elimination of Ethers from Bisphosphine-Ligated Benzylpalladium(II) Aryloxide Complexes. Angew. Chem. Int. Ed.   2011,  50,  7119–7123.

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248. Huang, Z.; Zhou, J. Hartwig, J.F. N-H Activation of Hydrazines by Iridium(I). Double N-H Activation to Form Iridium Aminonitrene Complexes. J. Am. Chem. Soc.   2010,  132,  11458-11460.

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239. Marquard, S.L.; Rosenfeld, D.C.; Hartwig, J.F. C(sp3)-N Bond-Forming Reductive Elimination of Amines: Reactions of Bisphosphine-Ligated Benzylpalladium(II) Diarylamido Complexes. Angew. Chem. Int. Ed.  2010,  49,  793.

176. Zhao, P., Incarvito, C.D., and J. F. Hartwig Carbon-Oxygen Bond Formation between a Terminal Alkoxo Ligand and a Coordinated Olefin. Evidence for Olefin Insertion into a Rhodium-Alkoxide. J. Am. Chem. Soc.  2006,  128,  9642-9643.

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165. Zhao, P., Incarvito, C. D., and J. F. Hartwig Direct Observation of b-Aryl Eliminations from Rh(I) Alkoxides. J. Am. Chem. Soc.  2006,  128,  3124-3125.

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147. Zhao, P., Krug, C., and J. F. Hartwig Transfer of Amido Groups from Isolated Rhodium(I) Amides to Alkenes and Vinylarenes. J. Am. Chem. Soc.  2005,  127,  12066-12073.

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146. Zhao, P. and J. F. Hartwig b-Aryl Eliminations from Rh(I) Iminyl Complexes. J. Am. Chem. Soc.  2005,  127,  11618-11619.

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143. Krug, C. and J. F. Hartwig Imine Insertion into a Late Metal-Carbon Bond To Form a Stable Amido Complex. J. Am. Chem. Soc.  2004,  126,  2694-2695.

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95. Krug, C. and J. F. Hartwig Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. J. Am. Chem. Soc.  2002,  124,  1674-1679.

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71. Zhao, J., Hesslink, H., and J. F. Hartwig Mechanism of b-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. J. Am. Chem. Soc.  2001,  123,  7220-7227.

66. Ishiyama, T. and J. Hartwig A Heck-type reaction involving carbon-heteroatom double bonds. Rhodium(I)-catalyzed coupling of aryl halides with N-pyrazyl aldimines. J. Am. Chem. Soc.  2000,  122,  12043-12044.

51. Driver, M. S. and J. F. Hartwig Oxidative addition and reductive elimination reactions of trans-[Ir(PPh3)2(CO)(NC4H4)] and trans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)] including N-H bond-forming reductive elimination of pyrrole. Organometallics  1998,  17,  1134-1143.

37. Driver, M. S. and J. F. Hartwig Energetics and mechanism of alkylamine N-H bond cleavage by palladium hydroxides: N-H activation by unusual acid-base chemistry. Organometallics  1997,  16,  5706-5715.

36. Driver, M. S. and J. F. Hartwig Carbon-nitrogen-bond-forming reductive elimination of arylamines from palladium(II) phosphine complexes. J. Am. Chem. Soc.  1997,  119,  8232-8245.

26. Driver, M. S. and J. F. Hartwig General N-H activation of primary alkylamines by a late transition-metal complex. J. Am. Chem. Soc.  1996,  118,  4206-4207.

23. Hartwig, J. F. Directly-observed b-hydrogen elimination of a late transition metal amido complex and unusual fate of imine byproducts. J. Am. Chem. Soc.  1996,  118,  7010-7011.