Reactivity of Tungstenocene with B-B and B-H Bonds versus C-H Bonds

The selectivity for addition of the BB bond of Cat'BBCat' (Cat' = 4-tBuC6H3O2) to [Cp2W] even in the presence of reactive C
H bonds in the solvent benzene is remarkable. In contrast to facile B
B cleavage, B
H bond formation occurred upon photolysis of [Cp2W(H)(BCat)] (Cat = C6H4O2). This facile cleavage of B
B bonds and the preferred formation of B
H bonds contrasts with the typical selectivities for C
C and C
H activation reactions. The formation and some reactions of tungstenocene are shown on the right.
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