Publications

C-C Bond Forming Cross-Couplings C-X Bond Forming Cross-Couplings Olefin Functionalization Iridium-Catalyzed Allylic Substitution C-H Bond Functionalization Catalysis for Sustainable Energy & Polymers Fluorination and Fluoroalkylation Main-Group-Transition Metal Organometallics New Organometallic Reactions High Throughput Screening Combining Organometallics with Biocatalysis Reviews Commentary and Book Chapters
Methods Mechanism
450. Kalkman, E. D.; Hartwig, J. F. Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes. J. Am. Chem. Soc.  2021,  143,  11741-11750.

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366. Jiao, Z.; Beiger, J.J.; Jin, Y.; Ge, S.; Zhou, J.; Hartwig, J.F. Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. J. Am. Chem. Soc.  2016,  138,  15980–15986.

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303. Gallego, D.; Brück, A.; Irran, E.; Meier, F.; Kaupp, M.; Driess, M.; Hartwig, J.F. From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction. J. Am. Chem. Soc.  2013,  135,  15617-15626.

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275. Klinkenberg, J.L.; Hartwig, J.F. Reductive Elimination from Arylpalladium Cyanide Complexes. J. Am. Chem. Soc.   2012,  134,  5758–5761.

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272. Huang, Z.; Hartwig, J.F. Copper(I) Enolate Complexes in Alpha-Arylation Reactions: Synthesis, Reactivity, and Mechanism. Angew. Chem. Int. Ed.   2012,  51,  1028–1032.

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261. Carrow, B. P.; Hartwig, J. F. Distinguishing Between Pathways for Transmetalation in Suzuki-Miyaura Reactions. J. Am. Chem. Soc  2011,  133,  2116-2119.

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236. Carrow, B.P.; Hartwig, J.F. Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction. J. Am. Chem. Soc.  2009,  132,  79-81.

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226. Barrios-Landeros, F.; Carrow, B.P.; Hartwig, J.F Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes. J. Am. Chem. Soc.  2009,  131,  8141-8154.

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217. Alexanian, E.J.; Hartwig, J.F. Mechanistic Study of β-Hydrogen Elimination from Organoplatinum(II) Enolate Complexes. J. Am. Chem. Soc.  2008,  130,  15627-15635.

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206. Barrios-Landeros, F., Carrow, B.P., and J.F. Hartwig Autocatalytic Oxidative Addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br).. J. Am. Chem. Soc.  2008,  130,  5842-5843.

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144. Culkin, D. A. and J. F. Hartwig Carbon-Carbon Bond-Forming Reductive Elimination from Arylpalladium Complexes Containing Functionalized Alkyl Groups. Influence of Ligand Steric and Electronic Properties on Structure, Stability, and Reactivity. Organometallics  2004,  23,  3398-3416.

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137. Roy, A. H. and J. F. Hartwig Oxidative Addition of Aryl Sulfonates to Palladium(0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism. Organometallics  2004,  23,  194-202.

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136. Roy, A. H. and J. F. Hartwig Reductive Elimination of Aryl Halides upon Addition of Hindered Alkylphosphines to Dimeric Arylpalladium(II) Halide Complexes. Organometallics  2004,  23,  1533-1541.

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132. Stambuli, J. P., Incarvito, C. D., Buhl, M. and J. F. Hartwig Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction. J. Am. Chem. Soc.  2004,  126,  1184-1194.

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130. Yamashita, M. and J. F. Hartwig Synthesis, Structure, and Reductive Elimination Chemistry of Three-Coordinate Arylpalladium Amido Complexes. J. Am. Chem. Soc.  2004,  126,  5344-5345.

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119. Liu, X. and J. F. Hartwig Palladium-catalyzed a-arylation of azlactones to form quaternary amino acid derivatives.. Org. Lett.  2003,  5,  1915-1918.

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