449. Fuentes, M. A.; Gava, R.; Saper, N. I.; Romero, E.; Caballero, A.; Hartwig, J. F.; Pérez, P. J. Copper-Catalyzed Dehydrogenative Amidation of Light Alkanes. Angew. Chem. Int. Ed.   202160,  18467-18471.

447. Fawcett, A.; Keller, M.J.; Herrera, Z.; Hartwig, J.F. Site Selective Chlorination of C(sp3)​-​H Bonds Suitable for Late-​Stage Functionalization. Angew. Chem. Int. Ed.  202160,  8276-8283.

439. Qiu, Y.; Hartwig, J.F. Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp3)–H Bonds. J. Am. Chem. Soc.  2020142,  19239-19248.

425. Su, B; Bunescu, A.; Qiu, Y.; Zuend, S.J.; Ernst, M.; Hartwig, J.F. Palladium-Catalyzed Oxidation of β-C(sp3)–H Bonds of Primary Alkylamines through a Rare Four-Membered Palladacycle Intermediate. J. Am. Chem. Soc.  2020142,  7912-7919.

408. He, Z.T., Hartwig, J.F. Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy. J. Am. Chem. Soc.  2019141,  11749-11753.

372. Jin, Y.; Chen, M.; Ge, S.; Hartwig, J.F. Palladium-Catalyzed, Enantioselective α‑Arylation of α‑Fluorooxindoles. Org. Lett.  201719,  1390–1393.

371. Litman, Z.C.; Sharma, A.; Hartwig, J.F. Oxidation of Hindered Allylic C-h Bonds with Applications to the Functionalization of Complex Molecules. ACS Catal.  20177,  1998-2001.

363. Karimov, R.R.; Sharma, A.; Hartwig, J.F. Late Stage Azidation of Complex Molecules. ACS Cent. Sci.  20162,  715-724.

331. Sharma, A.; Hartwig, J.H. Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization. Nature  2015517,  600-604.

330. Tran, B. L.; Driess, M.; Hartwig, J. F. Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes. J. Am. Chem. Soc.  2014136,  17292-17301.

323. Fier, P.S.; Hartwig, J.F. Synthesis and Late-Stage Functionalization of Complex Molecules through C−H Fluorination and Nucleophilic Aromatic Substitution. J. Am. Chem. Soc.  2014136,  10139-10147.

311. Tran, B.L.; Li, B.; Driess, M.; Hartwig, J.F. Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes. J. Am. Chem. Soc.  2014136,  2555-2563.

305. Fier, P.S.; Hartwig, J.F. Selective C-H Fluorination of Pyridines and Diazines Inspired by a Classic Amination Reaction. Science  2013342,  956-960.

297. Shrestha, R.; Mukherjee, P.; Tan, Y.; Litman, Z.C.; Hartwig, J.F. Sterically Controlled, Palladium-Catalyzed Intermolecular Amination of Arenes. J. Am. Chem. Soc.  2013135,  8480-8483.

273. Tan, Y.; Barrios-Landeros, F; Hartwig, J.F. Mechanistic Studies on Direct Arylation of Pyridine N-Oxide: Evidence for Cooperative Catalysis between Two Distinct Palladium Centers. J. Am. Chem. Soc.   2012134,  3683–3686.

262. Tan, Y.; Hartwig, J. F. Assessment of the Intermediacy of Arylpalladium Carboxylate Complexes in the Direct Arylation of Benzene: Evidence for C-H Bond Cleavage by ‘Ligandless’ Species. J. Am. Chem. Soc  2011133,  3308-3311.

243. Tan, Y.; Hartwig, J.F. Palladium-Catalyzed Amination of Aromatic C–H Bonds with Oxime Esters. J. Am. Chem. Soc.   2010132,  3676-3677.

223. Zhou, J.; Hartwig, J.F. Iridium-Catalyzed H/D Exchange at Vinyl Groups without Olefin Isomerization. Angew. Chem. Int. Ed.  200847,  5783-5787.

218. Herzon, S.B.; Hartwig, J.F. Hydroaminoalkylation of Unactivated Olefins with Dialkylamines. J. Am. Chem. Soc.  2008130,  14940–14941.