PUBLICATIONS

438. Wang, J.Y.; Choi, K.; Zuend, S.J.; Borate, K.; Hartwig, J.F. Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine. Angew. Chem. Int. Ed.  202060,  399-408.



433. Hartwig, J.F.; Shaughnessy, K.H.; Shekhar, S.; Green, R.A. Palladium-Catalyzed Amination of Aryl Halides. Organic Reactions  2020100,  853-943.

404. Haydl, A.M., Hartwig, J.F. Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters. Org. Lett.  201921,  1337-1341.



338. Brusoe, A.T.; Hartwig, J.F. Palladium-Catalyzed Arylation of Fluoroalkylamines. J. Am. Chem. Soc.  2015137,  8460–8468.



332. Green, R.A.; Hartwig, J.F. Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts. Angew. Chem. Int. Ed.  201554,  3768-3772.



322. Green, R.A.; Hartwig, J.F. Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts. Org. Lett.  201416,  4388−4391.



310. Ge. S.; Green, R.A.; Hartwig, J.F. Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex. J. Am. Chem. Soc.  2014136,  1617-1627.



292. Fier, P.S.; Luo, J.; Hartwig, J.F. Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex. J. Am. Chem. Soc.  2013135,  2552−2559.



246. Fernandez-Rodriguez, M.A.; Hartwig, J.F. One-Pot Synthesis of Unsymmetrical Diaryl Thioethers by Palladium-Catalyzed Coupling of Two Aryl Bromides and a Thiol Surrogate. Chem. Eur. J.  201016,  2355-2359.



230. Vo, G.D.; Hartwig, J.F. Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines. J. Am. Chem. Soc.  2009131,  11049-11061.



224. Fernandez-Rodríguez, M.A.; Hartwig, J.F. A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides. J. Org. Chem.  200974,  1663-1672.



222. Hartwig, J.F. Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides. Acc. Chem. Res.  200841,  1534-1544.



216. Ogata, T.; Hartwig, J.F. Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature. J. Am. Chem. Soc. (Communication)  2008130,  13848-13849.



207. Shen, Q., Ogata, T., and J.F. Hartwig Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides and Iodides: Scope and Structure-Activity Relationships.. J. Am. Chem. Soc.  2008130,  6586-6596.



195. Shen, Q. and J. F. Hartwig Lewis Acid Acceleration of C-N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides. J. Am. Chem. Soc.  2007129,  7734-7735.



182. Fernandez-Rodríguez, M. A., Shen, Q., and J. F. Hartwig Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols. Chem. Eur. J.  200612,  7782-7796.



177. Shen, Q., and J. F. Hartwig Palladium-Catalyzed Coupling of Ammonia and Lithium Amide with Aryl Halides. J. Am. Chem. Soc.  2006128,  10028-10029.



168. Fernández-Rodríguez, M. A., Shen, Q., and J. F. Hartwig A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols. J. Am. Chem. Soc.  2006128,  2180-2181.



164. Barrios-Landeros, F. and J. F. Hartwig Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands. J. Am. Chem. Soc.  2005127,  6944-6945.



163. Bae, C., Hartwig, J. F., Boaen Harris, N. K., Long, R. O., Anderson, K. S., and M. A. Hillmyer Catalytic Hydroxylation of Polypropylenes. J. Am. Chem. Soc.  2005127,  767-776.



158. Lee, D.-Y. and J. F. Hartwig Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates. Org. Lett.  20057,  1169-1172.



154. Shen, Q., Shekhar, S., Stambuli, J. P., and J. F. Hartwig Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles.. Angew. Chem. Int. Ed.  200544,  1371-1375.

149. Zhao, J., Goldman, A. S., and J. F. Hartwig Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex. Science  2005307,  1080-1082.

142. Krug, C. and J. F. Hartwig Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions. Organometallics  200423,  4594-4607.



135. Shekhar, S. and J. F. Hartwig Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes.. J. Am. Chem. Soc.  2004126,  13016-13027.



125. Hooper, M. W., Utsunomiya, M., and J. F. Hartwig Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. J. Org. Chem.  200368,  2861-2873.



124. Hooper, M. W. and J. F. Hartwig Understanding the Coupling of Heteroaromatic Substrates: Synthesis, Structures, and Reductive Eliminations of Heteroarylpalladium Amido Complexes. Organometallics  200322,  3394-3403.



113. Stauffer, S. R. and J. F. Hartwig Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study.. J. Am. Chem. Soc.  2003125,  6977-6985.



94. Kuwano, R., Utsunomiya, M., and J. F. Hartwig Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. J. Org. Chem.  200267,  6479-6486.



90. Ranasinghe, M. I., Varnavski, O. P., Pawlas, J., Hauck, S. I., Louie, J., Hartwig, J. F., and T. Goodson III Femtosecond excitation energy transport in triarylamine dendrimers. J. Am. Chem. Soc.  2002124,  6520-6521.



83. Chae, H. K., Eddaoudi, M., Kim, J., Hauck, S. I., Hartwig, J. F., O'Keeffe, M., and O. M. Yaghi Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1). J. Am. Chem. Soc.  2001123,  11482-11483.

77. Lee, S., M. Jorgensen, and J. F. Hartwig Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Org. Lett.  20013,  2729-2732.



63. Stauffer, S. R., Lee, S., Stambuli, J. P., Hauck, S. I., and J. F. Hartwig High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Org. Lett.  20002,  1423-1426.



60. Goodson, F. E., Hauck, S. I., and J. F. Hartwig Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines. J. Am. Chem. Soc.  1999121,  7527-7539.

58. Hartwig, J. F., Kawatsura, M., Hauck, S. I., Shaughnessy, K. H., and L. M. Alcazar-Roman Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand. J. Org. Chem.  199964,  5575-5580.



57. Hauck, S. I., Lakshmi, K. V. and J. F. Hartwig Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals. Org. Lett.  19991,  2057-2060.



55. Mann, G., Incarvito, C. D., Rheingold, A. L., and J. F. Hartwig Palladium-catalyzed C-O coupling involving unactivated aryl halides. Sterically induced reductive elimination to form the C-O bond in diaryl ethers. J. Am. Chem. Soc.  1999121,  3224-3225.

50. Goodson, F. E. and J. F. Hartwig Regiodefined poly(N-arylaniline)s and donor-acceptor copolymers via palladium-mediated amination chemistry. Macromolecules  199831,  1700-1703.

49. Hamann, B. C. and J. F. Hartwig Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates. J. Am. Chem. Soc.  1998120,  12706-12706.

44. Hartwig, J. F. Synthesis, structure, and reactivity of a palladium hydrazonato complex: A new type of reductive elimination reaction to form C-N bonds and catalytic arylation of benzophenone hydrazone. Angew. Chem. Int. Ed.  199837,  2090-2093.

43. Louie, J. and J. F. Hartwig The largest discrete oligo(m-aniline). An exponential growth strategy using palladium-catalyzed amination of aryl sulfonates. Macromolecules  199831,  6737-6739.

41. Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes. J. Am. Chem. Soc.  1998120,  827-828.

38. Baranano, D.; Mann, G., and Hartwig, J. F. Nickel and palladium-catalyzed cross-couplings that form carbon-heteroatom and carbon-element bonds. Current Organic Chemistry  19971,  287-305.

33. Louie, J., Hartwig, J. F., and A. J. Fry Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination. J. Am. Chem. Soc.  1997119,  11695-11696.

32. Louie, J., Driver, M. S., Hamann, B. C., and J. F. Hartwig Palladium-catalyzed amination of aryl triflates and importance of triflate addition rate. J. Org. Chem.  199762,  1268-1273.



31. Mann, G. and J. F. Hartwig Palladium-catalyzed formation of diaryl ethers from aryl bromides. Electron poor phosphines enhance reaction yields. Tetrahedron Letters  199738,  8005-8008.

30. Mann, G. and J. F. Hartwig Nickel- vs palladium-catalyzed synthesis of protected phenols from aryl halides. J. Org. Chem.  199762,  5413-5418.



27. Driver, M. S. and J. F. Hartwig A second-generation catalyst for aryl halide amination: Mixed secondary amines from aryl halides and primary amines catalyzed by (DPPF)PdCl2. J. Am. Chem. Soc.  1996118,  7217-7218.

9. Louie, J. and J. F. Hartwig Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides - Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. Tetrahedron Letters  199536,  3609-3612.