438. Wang, J.Y.; Choi, K.; Zuend, S.J.; Borate, K.; Hartwig, J.F.
Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine.
Angew. Chem. Int. Ed.2020,
60, 399-408.
322. Green, R.A.; Hartwig, J.F.
Palladium-Catalyzed Amination of Aryl Chlorides and Bromides with Ammonium Salts.
Org. Lett.2014,
16, 4388−4391.
310. Ge. S.; Green, R.A.; Hartwig, J.F.
Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex.
J. Am. Chem. Soc.2014,
136, 1617-1627.
292. Fier, P.S.; Luo, J.; Hartwig, J.F.
Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex.
J. Am. Chem. Soc.2013,
135, 2552−2559.
246. Fernandez-Rodriguez, M.A.; Hartwig, J.F.
One-Pot Synthesis of Unsymmetrical Diaryl Thioethers by Palladium-Catalyzed Coupling of Two Aryl Bromides and a Thiol Surrogate.
Chem. Eur. J.2010,
16, 2355-2359.
230. Vo, G.D.; Hartwig, J.F.
Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines.
J. Am. Chem. Soc.2009,
131, 11049-11061.
224. Fernandez-Rodríguez, M.A.; Hartwig, J.F.
A General, Efficient, and Functional-Group-Tolerant Catalyst System for the Palladium-Catalyzed Thioetherification of Aryl Bromides and Iodides.
J. Org. Chem.2009,
74, 1663-1672.
222. Hartwig, J.F.
Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides.
Acc. Chem. Res.2008,
41, 1534-1544.
207. Shen, Q., Ogata, T., and J.F. Hartwig
Highly Reactive, General and Long-Lived Catalysts for Palladium-Catalyzed Amination of Heteroaryl and Aryl Chlorides, Bromides and Iodides: Scope and Structure-Activity Relationships..
J. Am. Chem. Soc.2008,
130, 6586-6596.
195. Shen, Q. and J. F. Hartwig
Lewis Acid Acceleration of C-N Bond-Forming Reductive Elimination from Heteroarylpalladium Complexes and Catalytic Amidation of Heteroaryl Bromides.
J. Am. Chem. Soc.2007,
129, 7734-7735.
182. Fernandez-Rodríguez, M. A., Shen, Q., and J. F. Hartwig
Highly Efficient and Functional-Group-Tolerant Catalysts for the Palladium-Catalyzed Coupling of Aryl Chlorides with Thiols.
Chem. Eur. J.2006,
12, 7782-7796.
168. Fernández-Rodríguez, M. A., Shen, Q., and J. F. Hartwig
A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols.
J. Am. Chem. Soc.2006,
128, 2180-2181.
164. Barrios-Landeros, F. and J. F. Hartwig
Distinct Mechanisms for the Oxidative Addition of Chloro-, Bromo-, and Iodoarenes to a Bisphosphine Palladium(0) Complex with Hindered Ligands.
J. Am. Chem. Soc.2005,
127, 6944-6945.
163. Bae, C., Hartwig, J. F., Boaen Harris, N. K., Long, R. O., Anderson, K. S., and M. A. Hillmyer
Catalytic Hydroxylation of Polypropylenes.
J. Am. Chem. Soc.2005,
127, 767-776.
158. Lee, D.-Y. and J. F. Hartwig
Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates.
Org. Lett.2005,
7, 1169-1172.
154. Shen, Q., Shekhar, S., Stambuli, J. P., and J. F. Hartwig
Highly Reactive, General, and Long-Lived Catalysts for Coupling Heteroaryl and Aryl Chlorides with Primary Nitrogen Nucleophiles..
Angew. Chem. Int. Ed.2005,
44, 1371-1375.
149. Zhao, J., Goldman, A. S., and J. F. Hartwig
Oxidative Addition of Ammonia to Form a Stable Monomeric Amido Hydride Complex.
Science2005,
307, 1080-1082.
142. Krug, C. and J. F. Hartwig
Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions.
Organometallics2004,
23, 4594-4607.
135. Shekhar, S. and J. F. Hartwig
Distinct Electronic Effects on Reductive Eliminations of Symmetrical and Unsymmetrical Bis-Aryl Platinum Complexes..
J. Am. Chem. Soc.2004,
126, 13016-13027.
125. Hooper, M. W., Utsunomiya, M., and J. F. Hartwig
Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides.
J. Org. Chem.2003,
68, 2861-2873.
124. Hooper, M. W. and J. F. Hartwig
Understanding the Coupling of Heteroaromatic Substrates: Synthesis, Structures, and Reductive Eliminations of Heteroarylpalladium Amido Complexes.
Organometallics2003,
22, 3394-3403.
113. Stauffer, S. R. and J. F. Hartwig
Fluorescence Resonance Energy Transfer (FRET) as a High-Throughput Assay for Coupling Reactions. Arylation of Amines as a Case Study..
J. Am. Chem. Soc.2003,
125, 6977-6985.
94. Kuwano, R., Utsunomiya, M., and J. F. Hartwig
Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
J. Org. Chem.2002,
67, 6479-6486.
90. Ranasinghe, M. I., Varnavski, O. P., Pawlas, J., Hauck, S. I., Louie, J., Hartwig, J. F., and T. Goodson III
Femtosecond excitation energy transport in triarylamine dendrimers.
J. Am. Chem. Soc.2002,
124, 6520-6521.
83. Chae, H. K., Eddaoudi, M., Kim, J., Hauck, S. I., Hartwig, J. F., O'Keeffe, M., and O. M. Yaghi
Tertiary building units: Synthesis, structure, and porosity of a metal-organic dendrimer framework (MODF-1).
J. Am. Chem. Soc.2001,
123, 11482-11483.
77. Lee, S., M. Jorgensen, and J. F. Hartwig
Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.
Org. Lett.2001,
3, 2729-2732.
63. Stauffer, S. R., Lee, S., Stambuli, J. P., Hauck, S. I., and J. F. Hartwig
High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands.
Org. Lett.2000,
2, 1423-1426.
60. Goodson, F. E., Hauck, S. I., and J. F. Hartwig
Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines.
J. Am. Chem. Soc.1999,
121, 7527-7539.
58. Hartwig, J. F., Kawatsura, M., Hauck, S. I., Shaughnessy, K. H., and L. M. Alcazar-Roman
Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand.
J. Org. Chem.1999,
64, 5575-5580.
57. Hauck, S. I., Lakshmi, K. V. and J. F. Hartwig
Tetraazacyclophanes by palladium-catalyzed aromatic amination. Geometrically defined, stable, high-spin diradicals.
Org. Lett.1999,
1, 2057-2060.
55. Mann, G., Incarvito, C. D., Rheingold, A. L., and J. F. Hartwig
Palladium-catalyzed C-O coupling involving unactivated aryl halides. Sterically induced reductive elimination to form the C-O bond in diaryl ethers.
J. Am. Chem. Soc.1999,
121, 3224-3225.
50. Goodson, F. E. and J. F. Hartwig
Regiodefined poly(N-arylaniline)s and donor-acceptor copolymers via palladium-mediated amination chemistry.
Macromolecules1998,
31, 1700-1703.
49. Hamann, B. C. and J. F. Hartwig
Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates.
J. Am. Chem. Soc.1998,
120, 12706-12706.
44. Hartwig, J. F.
Synthesis, structure, and reactivity of a palladium hydrazonato complex: A new type of reductive elimination reaction to form C-N bonds and catalytic arylation of benzophenone hydrazone.
Angew. Chem. Int. Ed.1998,
37, 2090-2093.
43. Louie, J. and J. F. Hartwig
The largest discrete oligo(m-aniline). An exponential growth strategy using palladium-catalyzed amination of aryl sulfonates.
Macromolecules1998,
31, 6737-6739.
41. Mann, G., Hartwig, J. F., Driver, M. S., and C. Fernandez-Rivas
Palladium-catalyzed C-N(sp2) bond formation: N-arylation of aromatic and unsaturated nitrogen and the reductive elimination chemistry of palladium azolyl and methyleneamido complexes.
J. Am. Chem. Soc.1998,
120, 827-828.
38. Baranano, D.; Mann, G., and Hartwig, J. F.
Nickel and palladium-catalyzed cross-couplings that form carbon-heteroatom and carbon-element bonds.
Current Organic Chemistry1997,
1, 287-305.
33. Louie, J., Hartwig, J. F., and A. J. Fry
Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination.
J. Am. Chem. Soc.1997,
119, 11695-11696.
32. Louie, J., Driver, M. S., Hamann, B. C., and J. F. Hartwig
Palladium-catalyzed amination of aryl triflates and importance of triflate addition rate.
J. Org. Chem.1997,
62, 1268-1273.
31. Mann, G. and J. F. Hartwig
Palladium-catalyzed formation of diaryl ethers from aryl bromides. Electron poor phosphines enhance reaction yields.
Tetrahedron Letters1997,
38, 8005-8008.
30. Mann, G. and J. F. Hartwig
Nickel- vs palladium-catalyzed synthesis of protected phenols from aryl halides.
J. Org. Chem.1997,
62, 5413-5418.
27. Driver, M. S. and J. F. Hartwig
A second-generation catalyst for aryl halide amination: Mixed secondary amines from aryl halides and primary amines catalyzed by (DPPF)PdCl2.
J. Am. Chem. Soc.1996,
118, 7217-7218.
9. Louie, J. and J. F. Hartwig
Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides - Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents.
Tetrahedron Letters1995,
36, 3609-3612.
