Publications

401. Jiang, Q., Peacock, D.M., Hartwig, J.F., Cundari, T.R. Carbon (sp³)-nitrogen bond-forming reductive elimination from phosphine-ligated alkylpalladium (II) amide complexes: A DFT study. Tetrahedron  2019,  75,  137-143.

285. Chen, C.; Weng, Z.; Hartwig, J.F. Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics  2012,  31,  8031–8036.

254. Giri, R.: Hartwig, J.F. Cu(I) Amido Complexes in the Ullmann Reaction. Reactions of Cu(I)-Amido Complexes with Iodoarenes with and without Autocatalysis by CuI. J. Am. Chem. Soc.   2010,  132,  15860-15863.

250. Klinkenberg, J.L.; Hartwig, J.F. Slow Reductive Elimination from Arylpalladium Parent Amido Complexes. J. Am. Chem. Soc.   2010,  132,  11830-11833.

242. Tye, J.W.; Weng, Z.; Giri, R.; Hartwig J.F. Copper(I) Phenoxide Complexes in the Etherification of Aryl Halides. Angew. Chem. Int. Ed.   2010,  49,  2185-2189.

227. Alvaro, E.; Hartwig, J.F. Resting State and Elementary Steps of the Coupling of Aryl Halides with Thiols Catalyzed by Alkylbisphosphine Complexes of Palladium. J. Am. Chem. Soc.  2009,  131,  7858–7868.

213. Shen, Q. and J.F. Hartwig [(CyPF-tBu)PdCl₂]: An Air-Stable, One-Component, Highly Efficient Catalyst for Amination of Heteroaryl and Aryl Halides.. Org. Lett.  2008,  18,  4109-4112.

212. Tye, J.W., Weng, Z., Johns, A. M., Incarvito, C. D., and J. F. Hartwig Copper Complexes of Anionic Nitrogen Ligands in the Amidation and Imidation of Aryl Halides.. J. Am. Chem. Soc.  2008,  130,  9971-9983.

199. Stambuli, J.P., Weng, Z., Incarvito, C.D., and J. F. Hartwig Reductive Elimination of Ether from T-Shaped, Monomeric Arylpalladium Alkoxides.. Angew. Chem. Int. Ed.  2007,  46,  7674-7677.

187. Shekhar, S., and J. F. Hartwig Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd[P(tBu3)]2. Organometallics  2007,  26,  340-351.

184. Johns, A. M, Tye, J. W., and J. F. Hartwig Relative Rates for the Aminations of h3-Allyl and h3-Benzyl Complexes of Palladium. J. Am. Chem. Soc.  2006,  128,  16010-16011.

175. Fujita, K.I., Yamashita, M, Puschmann, F., Alvarez-Falcon, M.M., Incarvito, C.D., and J. F. Hartwig Organometallic Chemistry from Amidate Complexes. Reductive elimination of N-Aryl Amidates from Palladium(II). J. Am. Chem. Soc.  2006,  128,  9044-9045.

167. Shekhar, S., Ryberg, P., and J. F. Hartwig Oxidative Addition of Phenyl Bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for Addition to Pd(BINAP). Org. Lett.  2006,  8,  851-854.

166. Shekhar, S., Ryberg, P., Hartwig, J. F., Mathew, J. S., Blackmond, D. G., Strieter, E. R., and S. L. Buchwald Reevaluation of the Mechanism of the Amination of Aryl Halides Catalyzed by BINAP-Ligated Palladium Complexes. J. Am. Chem. Soc.  2006,  128,  3584-3591.

117. Mann, G., Shelby, Q., Roy, A. H., and J. F. Hartwig Electronic and Steric Effects on the Reductive Elimination of Diaryl Ethers from Palladium(II). Organometallics  2003,  22,  2775-2789.

116. Roy, A. H. and J. F. Hartwig Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes. J. Am. Chem. Soc.  2003,  125,  13944-13945.

108. Yamashita, M., Cuevas Vicario, J. V., and J. F. Hartwig Trans Influence on the Rate of Reductive Elimination. Reductive Elimination of Amines from Isomeric Arylpalladium Amides with Unsymmetrical Coordination Spheres. J. Am. Chem. Soc.  2003,  125,  16347-16360.

104. Alcazar-Roman, L. M. and J. F. Hartwig Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine. Organometallics  2002,  21,  491-502.

87. Stambuli, J. P., Buhl, M., and J. F. Hartwig Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc.  2002,  124,  9346-9347.

84. Alcazar-Roman, L. M. and J. F. Hartwig Mechanism of aryl chloride amination: Base-induced oxidative addition. J. Am. Chem. Soc.  2001,  123,  12905-12906.

74. Roy, A. H. and J. F. Hartwig Reductive elimination of aryl halides from palladium(II). J. Am. Chem. Soc.  2001,  123,  1232-1233.

70. Shelby, Q.; Kataoka, N.; Mann, G.; Hartwig, J.F. Unusual in situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C-O Bond Formation. J. Am. Chem. Soc.  2000,  122,  10718-10719.

69. Alcazar-Roman, L. M., Hartwig, J. F., Rheingold, A. L., Liable-Sands, L. M., and I. A. Guzei Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition. J. Am. Chem. Soc.  2000,  122,  4618-4630.

47. Hamann, B. C. and J. F. Hartwig Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations. J. Am. Chem. Soc.  1998,  120,  3694-3703.

46. Hartwig, J. F. Carbon-heteroatom bond-forming reductive eliminations of amines, ethers, and sulfides. Acc. Chem. Res.  1998,  31,  852-860.

45. Hartwig, J. F. Transition metal catalyzed synthesis of arylamines and aryl ethers from aryl halides and triflates: Scope and mechanism. Angew. Chem. Int. Ed.  1998,  37,  2047-2067.

42. Mann, G., Baranano, D., Hartwig, J. F., Rheingold, A. L., and I. A. Guzei Carbon-sulfur bond-forming reductive elimination involving sp-, sp2-, and sp3-hybridized carbon. Mechanism, steric effects, and electronic effects on sulfide formation. J. Am. Chem. Soc.  1998,  120,  9205-9219.

22. Hartwig, J. F., Richards, S., Baranano, D., and F. Paul Influences on the relative rates for C-N bond-forming reductive elimination and beta-hydrogen elimination of amides. A case study on the origins of competing reduction in the palladium-catalyzed amination of aryl halides. J. Am. Chem. Soc.  1996,  118,  3626-3633.

17. Louie, J., F. Paul, and J. F. Hartwig Catalysis with platinum-group alkylamido complexes, the active palladium amide in catalytic aryl halide aminations as deduced from kinetic data and independent generation. Organometallics  1996,  15,  2794-2805.

16. Mann, G. and J. F. Hartwig Palladium alkoxides: Potential intermediacy in catalytic amination, reductive elimination of ethers, and catalytic etheration. Comments on alcohol elimination from Ir(III). J. Am. Chem. Soc.  1996,  118,  13109-13110.

14. Baranano, D. and J. F. Hartwig Carbon-Heteroatom Bond-Forming Reductive Elimination - Mechanism, Importance of Trapping Reagents, and Unusual Electronic Effects During Formation of Aryl Sulfides. J. Am. Chem. Soc.  1995,  117,  2937-2938.

13. Driver, M. S. and J. F. Hartwig A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by 3-Coordinate Intermediates. J. Am. Chem. Soc.  1995,  117,  4708-4709.

12. Paul, F., Patt, J., and J. F. Hartwig Structural Characterization and Simple Synthesis of (Pd[P(O-Tol)3]2), Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides, and Corresponding Monometallic Amine Complexes. Organometallics  1995,  14,  3030-3039.

11. Hartwig, J. F. and F. Paul Oxidative Addition of Aryl Bromide after Dissociation of Phosphine from a 2-Coordinate Palladium(0) Complex, Bis(Tri-O-Tolylphosphine)Palladium(0). J. Am. Chem. Soc.  1995,  117,  5373-5374.

10. Louie, J. and J. F. Hartwig Transmetalation Involving Organotin Aryl, Thiolate, and Amide Compounds - an Unusual Type of Dissociative Ligand Substitution-Reaction. J. Am. Chem. Soc.  1995,  117,  11598-11599.

5. Paul, F., Patt, J., and J. F. Hartwig Palladium-Catalyzed Formation of Carbon-Nitrogen Bonds - Reaction Intermediates and Catalyst Improvements in the Hetero Cross-Coupling of Aryl Halides and Tin Amides. J. Am. Chem. Soc.  1994,  116,  5969-5970.