PUBLICATIONS

428. Karmel, C.; Hartwig, J.F. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds. J. Am. Chem. Soc.  2020142,  10494-10505.



420. Karmel, C.; Rubel, C.Z.; Kharitonova, E.V.; Hartwig, J.F. Iridium‐Catalyzed Silylation of Five‐Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl‐Imidazoline Ligand. Angew. Chem. Int. Ed.  202059,  6074-6081.



407. Hartwig, J.F., Romero, E.A. Iridium-catalyzed silylation of unactivated C-H bonds. Tetrahedron  201975,  4059-4070.



406. Karmel, C., Chen, Z., Hartwig, J.F. Iridium-Catalyzed Silylation of C–H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis. J. Am. Chem. Soc.  2019141,  7063-7072.



367. Su, B.; Zhou, T.; Li, X.; Shao, X.; Xu, P.; Wu, W.; Hartwig, J.F.; Shi, Z. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angew. Chem. Int. Ed.   201756,  1092–1096.



354. Lee, T.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angew. Chem. Int. Ed.  201655,  8723-8727.



335. Lee, T.; Wilson, T.W.; Berg, R.; Ryberg, P.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Arene C-H bonds: Desymmetrization of Diarylmethanols. J. Am. Chem. Soc.  2015137,  6742-6745.



333. Cheng, C.; Hartwig, J.F. Iridium-Catalyzed Silylation of Aryl C−H Bonds. J. Am. Chem. Soc.  2015137,  592-595.



325. Cheng, C.; Hartwig, J.F. Mechanism of the Rhodium-Catalyzed Silylation of Arene C−H Bonds. J. Am. Chem. Soc.  2014136,  12064-12072.



321. Li, B.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C−H Bonds for the Synthesis of 1,3-Diols. J. Am. Chem. Soc.  2014136,  6586-6589.



320. Li, Q.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic C-H Bonds Directed by a Secondary Amine. Angew. Chem. Int. Ed.  201453,  1-5.



313. Cheng, C.; Hartwig, J.F. Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol. Science.  2014343,  853-857.

300. Cheng, C.; Simmons, E.M.; Hartwig, J.H. Iridium-Catalyzed, Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH. Angew. Chem. Int. Ed.  201352,  8984 –8989.



274. Simmons, E.M.; Hartwig, J.F. Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol. Nature  2012483,  70–73.

152. Tsukada, N. and J. F. Hartwig Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C-H Bonds. J. Am. Chem. Soc.  2005127,  5022-5023.