Publications

C-C Bond Forming Cross-Couplings C-X Bond Forming Cross-Couplings Olefin Functionalization Iridium-Catalyzed Allylic Substitution C-H Bond Functionalization Catalysis for Sustainable Energy & Polymers Fluorination and Fluoroalkylation Main-Group-Transition Metal Organometallics New Organometallic Reactions High Throughput Screening Combining Organometallics with Biocatalysis Reviews Commentary and Book Chapters
C-H Borylation C-H Silylation Other C-H Functionalization
428. Karmel, C.; Hartwig, J.F. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C–H Bonds. J. Am. Chem. Soc.  2020,  142,  10494-10505.

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420. Karmel, C.; Rubel, C.Z.; Kharitonova, E.V.; Hartwig, J.F. Iridium‐Catalyzed Silylation of Five‐Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl‐Imidazoline Ligand. Angew. Chem. Int. Ed.  2020,  59,  6074-6081.

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407. Hartwig, J.F., Romero, E.A. Iridium-catalyzed silylation of unactivated C-H bonds. Tetrahedron  2019,  75,  4059-4070.

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406. Karmel, C., Chen, Z., Hartwig, J.F. Iridium-Catalyzed Silylation of C–H Bonds in Unactivated Arenes: A Sterically Encumbered Phenanthroline Ligand Accelerates Catalysis. J. Am. Chem. Soc.  2019,  141,  7063-7072.

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367. Su, B.; Zhou, T.; Li, X.; Shao, X.; Xu, P.; Wu, W.; Hartwig, J.F.; Shi, Z. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angew. Chem. Int. Ed.   2017,  56,  1092–1096.

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354. Lee, T.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angew. Chem. Int. Ed.  2016,  55,  8723-8727.

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335. Lee, T.; Wilson, T.W.; Berg, R.; Ryberg, P.; Hartwig, J.F. Rhodium-Catalyzed Enantioselective Silylation of Arene C-H bonds: Desymmetrization of Diarylmethanols. J. Am. Chem. Soc.  2015,  137,  6742-6745.

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333. Cheng, C.; Hartwig, J.F. Iridium-Catalyzed Silylation of Aryl C−H Bonds. J. Am. Chem. Soc.  2015,  137,  592-595.

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325. Cheng, C.; Hartwig, J.F. Mechanism of the Rhodium-Catalyzed Silylation of Arene C−H Bonds. J. Am. Chem. Soc.  2014,  136,  12064-12072.

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321. Li, B.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C−H Bonds for the Synthesis of 1,3-Diols. J. Am. Chem. Soc.  2014,  136,  6586-6589.

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320. Li, Q.; Driess, M.; Hartwig, J.F. Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic C-H Bonds Directed by a Secondary Amine. Angew. Chem. Int. Ed.  2014,  53,  1-5.

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313. Cheng, C.; Hartwig, J.F. Rhodium-Catalyzed Intermolecular C–H Silylation of Arenes with High Steric Regiocontrol. Science.  2014,  343,  853-857.

300. Cheng, C.; Simmons, E.M.; Hartwig, J.H. Iridium-Catalyzed, Diastereoselective Dehydrogenative Silylation of Terminal Alkenes with (TMSO)2MeSiH. Angew. Chem. Int. Ed.  2013,  52,  8984 –8989.

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274. Simmons, E.M.; Hartwig, J.F. Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol. Nature  2012,  483,  70–73.

152. Tsukada, N. and J. F. Hartwig Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C-H Bonds. J. Am. Chem. Soc.  2005,  127,  5022-5023.

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