Publications

Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [Pd(allyl)Cl]2 and DPPF or Q-phos.

Vo, G.D., and J.F. Hartwig

Angew. Chem. Int. Ed., 2008, 47 (2127-2130)

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Palladium-Catalyzed &alpha;-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [Pd(allyl)Cl]<sub>2</sub> and DPPF or Q-phos.

Abstract

Pd source matters: A general method for palladium-catalyzed α-arylation of aldehydes (see scheme) was developed to couple linear and branched aldehydes with electron-poor and electron-rich bromo- and chloroarenes.
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